anionic polymerization

简明释义

阴离子聚合

英英释义

Anionic polymerization is a type of chain-growth polymerization where the active site of the growing polymer chain is a negatively charged ion (anion), which allows for the addition of monomers that have electron-deficient double bonds.

阴离子聚合是一种链增长聚合反应,其中生长聚合物链的活性位点是一个带负电荷的离子(阴离子),这使得可以添加具有缺电子双键的单体。

例句

1.The process of anionic polymerization is often used to create high-performance elastomers.

过程中的阴离子聚合常用于制造高性能弹性体。

2.One advantage of anionic polymerization is its ability to produce polymers with very narrow molecular weight distributions.

一个阴离子聚合的优势是能够生产具有非常窄的分子量分布的聚合物。

3.In the laboratory, we studied the kinetics of anionic polymerization to better understand its mechanism.

在实验室中,我们研究了阴离子聚合的动力学,以更好地理解其机制。

4.The synthesis of block copolymers often involves anionic polymerization techniques.

嵌段共聚物的合成通常涉及阴离子聚合技术。

5.Researchers are exploring new initiators for anionic polymerization to enhance reaction efficiency.

研究人员正在探索新的引发剂以增强阴离子聚合的反应效率。

作文

Anionic polymerization is a type of chain-growth polymerization that involves the reaction of anionic initiators with monomers to form polymers. This process is particularly significant in the field of materials science and polymer chemistry due to its ability to produce well-defined and high-molecular-weight polymers. The mechanism of anionic polymerization (阴离子聚合) involves the generation of a negatively charged species that initiates the polymerization process. These initiators can be alkali metals, organolithium compounds, or other strong bases that can effectively abstract a proton from the monomer, creating a reactive anion that can propagate the polymer chain.One of the most notable advantages of anionic polymerization (阴离子聚合) is its ability to control the molecular weight of the resulting polymer. By carefully managing the concentration of the initiator and the monomer, chemists can synthesize polymers with specific chain lengths. This level of control is crucial for applications that require precise material properties, such as in the production of elastomers and thermoplastics.Moreover, anionic polymerization (阴离子聚合) allows for the synthesis of block copolymers, where two or more different types of monomers are linked together in distinct blocks. This property is particularly useful in creating materials with tailored physical properties, such as improved strength or flexibility. The ability to manipulate the structure of the polymer at the molecular level opens up a wide range of possibilities in product development.The process of anionic polymerization (阴离子聚合) typically occurs in an inert atmosphere, such as nitrogen or argon, to prevent contamination from moisture or oxygen, which can terminate the polymerization process. The reaction usually takes place in a solvent that can stabilize the growing anionic species, ensuring that the polymerization proceeds smoothly. Common solvents include tetrahydrofuran (THF) and dimethyl sulfoxide (DMSO).In addition to its advantages, anionic polymerization (阴离子聚合) also has some limitations. For instance, it is generally restricted to certain types of monomers that can stabilize the negative charge. Monomers that are too reactive or have electron-withdrawing groups may not be suitable for this type of polymerization. Furthermore, the need for strict control over the reaction environment can complicate the process, making it less accessible for large-scale production compared to other methods.In conclusion, anionic polymerization (阴离子聚合) is a powerful technique in polymer chemistry that enables the synthesis of high-quality polymers with precise molecular weights and structures. Its applications range from industrial materials to advanced nanotechnology, showcasing its versatility and importance in modern science. As research continues to advance, we can expect further developments in this area, leading to even more innovative materials and applications in various fields.

相关单词

anionic

anionic详解:怎么读、什么意思、用法